纳滤分离铝锂过程研究          下载免费PDF全文

高琳  王怀有  赵有璟  王敏 《盐湖研究》2020,28(2)

本文探讨了纳滤分离Al~(3+)和Li~+的可行性,研究了含盐量和铝锂比对分离效率的影响,提出了从锂云母浸出液中分离回收锂的新方法。实验结果表明,纳滤膜对Al~(3+)和Li~+的截留率随含盐量的升高而降低,其中Li~+始终呈现负浓度梯度扩散的趋势,而Al~(3+)的截留率始终稳定在99%以上。当含盐量为45 g/L时,铝锂分离因子最高可达248.33,膜面相应Zeta电位的绝对值达到最大。随着溶液中铝锂比的变化,Al~(3+)和Li~+的截留率分别在不同铝锂比的条件下出现拐点,溶液的pH呈现先下降后上升最后下降的复杂趋势。本实验研究发现,DK膜能够在酸性环境下实现高效的铝锂分离和锂的浓缩,从而为锂云母浸出液中锂的提取提供新的思路。  相似文献   

Relocation of the Jinghe MS6.6 Earthquake Sequence on August 9, 2017 and Analysis of the Seismogenic Structure     

Liu Jianming  Gao Rong  Wang Qiong  Nie Xiaohong 《中国地震研究》2018,32(4):482-490

Based on the digital waveforms of the Xinjiang Digital Seismic Network,the Jinghe M_S6.6 earthquake sequence( M_L≥1. 0) were relocated by HypoDD,The characteristics of the spatial distribution and the seismogenic structure of this earthquake sequence were analyzed. The results show that the main shock is relocated at 44. 2639° N,82. 8294° E,and the initial rupture depth is 17. 6 km. The earthquake sequence clearly demonstrates a unilateral extension of about 20 km in the EW direction,and is mainly located at a depth of 7km-17 km. The depth profile along the aftershock direction shows that the focal depth of aftershocks tend to be shallower within 10 km to the west of the main shock,the focal depth of the aftershock sequence with the tail direction deflecting SW is deeper. The depth profile perpendicular to the earthquake sequence shows a gradual deepening of the seismic sequence from north to south,which indicates that the fault plane is dipping south.According to the focal mechanism solution,given by the Institute of Geophysics,China Earthquake Administration,and the geological structure of the seismic source region,it is inferred that the seismogenic structure of the Jinghe M_S 6.6 earthquake may be the eastern segment of the Kusongmuxieke fault.  相似文献   

An experimental investigation of the effects of thawed soil depth on rill flow velocity     

Xiaofeng Gao  Xiaonan Shi  Tingwu Lei  Huaqing Liu  Jiahui Yang 《水文研究》2021,35(2):e14043

Water flow velocity is an important hydraulic variable in hydrological and soil erosion models, and is greatly affected by freezing and thawing of the surface soil layer in cold high-altitude regions. The accurate measurement of rill flow velocity when impacted by the thawing process is critical to simulate runoff and sediment transport processes. In this study, an electrolyte tracer modelling method was used to measure rill flow velocity along a meadow soil slope at different thaw depths under simulated rainfall. Rill flow velocity was measured using four thawed soil depths (0, 1, 2 and 10 cm), four slope gradients (5°, 10°, 15° and 20°) and four rainfall intensities (30, 60, 90 and 120 mm·h⁻¹). The results showed that the increase in thawed soil depth caused a decrease in rill flow velocity, whereby the rate of this decrease was also diminishing. Whilst the rill flow velocity was positively correlated with slope gradient and rainfall intensity, the response of rill flow velocity to these influencing factors varied with thawed soil depth. The mechanism by which thawed soil depth influenced rill flow velocity was attributed to the consumption of runoff energy, slope surface roughness, and the headcut effect. Rill flow velocity was modelled by thawed soil depth, slope gradient and rainfall intensity using an empirical function. This function predicted values that were in good agreement with the measured data. These results provide the foundation for a better understanding of the effect of thawed soil depth on slope hydrology, erosion and the parameterization scheme for hydrological and soil erosion models.  相似文献   

国外无人反水雷特点及关键技术分析     

王久法  吴乔  高频  仝志永 《数字海洋与水下攻防》2020,3(5):382-386

许多国家将水雷视为一种重要的水中兵器，用于封锁对手、对抗强敌。针对现有反水雷装备存在的危险性高、部署速度慢、作战效率低等问题，国外海军将无人技术为代表的高新技术应用到反水雷领域，推出了多种新概念无人反水雷装备，综合运用猎、扫等多种手段，构建空中、水面、水下立体的无人反水雷装备体系，实现快速、安全、高效的反水雷作战能力，对未来反水雷作战产生重大影响。  相似文献   

西太平洋海域现场培养实验中挥发性卤代烃浓度的变化及其影响因素     

韩钰  何真  刘珊珊  高旭旭  杨桂朋 《海洋学报》2020,42(2):1-9

CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂是挥发性卤代烃4种重要成分，对大气化学产生重要影响。于2018年10月在西太平洋进行船基现场培养实验，研究微量元素Fe (50 nmol/L)、酸化(pH=7.9)、酸化(pH=7.9)和微量元素Fe (50 nmol/L)耦合作用、微量元素Fe (50 nmol/L)和N/P (16∶1)耦合作用及沙尘(4 mg/L)对浮游植物释放CH₃I、CHCl₃、C₂HCl₃和CH₂Br₂含量的影响。结果表明，与对照组相比，实验组CH₃I、C₂HCl₃和CH₂Br₂的释放均被不同程度抑制；CHCl₃的释放除添加沙尘时表现抑制作用外，其他条件下均为促进作用；实验组培养周期内叶绿素a浓度较高，而营养盐浓度变化规律不明显。总的来说，酸化和微量元素Fe可能是影响浮游植物释放挥发性卤代烃的重要限制因素，沙尘对促进浮游植物生长繁殖的影响更为显著。  相似文献   

长江口咸潮入侵变化特征及成因分析     

李文善  王慧  左常圣  董军兴  徐浩  潘嵩  金波文  高通 《海洋学报》2020,42(7):32-40

本文基于海洋站潮位观测数据、海平面变化影响调查信息以及长江口水文站径流量数据等，重点分析了2009?2018年长江口咸潮入侵的变化特征及其影响因素，分析结果表明:(1)长江口咸潮入侵季节变化特征明显。咸潮一般从每年的9?10月开始入侵，翌年4?5月结束。3月咸潮入侵次数最多，达12次。2009?2018年，长江口咸潮入侵次数和咸潮持续时间均呈下降趋势，2009年长江口咸潮入侵次数最多，达13次，时间均发生在10月至翌年的4月；咸潮持续时间年际变化较大，2011年咸潮入侵持续时间最长，累计为55 d。2015?2018年，咸潮入侵次数和入侵持续时间均明显减少，2018年没有监测到咸潮入侵过程。(2) 1?4月，长江口处于季节性低海平面期，且同期径流量少，但是受东亚季风影响，持续的增水过程使得增减水?径流量综合影响指数明显偏高，其中1月、2月、3月的影响指数分别为1.5、1.9和1.6，该时段长江口的咸潮入侵过程主要受增减水的影响。5?7月，长江口径流量明显增加，海平面?径流量综合影响指数均小于0，径流的作用强于海水上溯。8月，长江口径流量开始下降，虽然季节海平面较高，但是长江口呈现明显的减水过程，海平面?径流量和增减水?径流量的综合影响指数分别为0.1和?1.6，基本不会发生咸潮入侵。9月，长江口处于季节高海平面期，并且以增水为主，海平面?径流量和增减水?径流量的综合影响指数较大，分别为1.2和1.0，易发生咸潮入侵。10月、11月长江口海平面?径流量的综合影响指数分别为1.5和0.8，径流影响弱于海水上溯，易发生咸潮入侵。(3) 2009?2018年发生的48次咸潮入侵过程有2/3恰逢天文大潮。在某些年份长江口沿海基础海平面偏高，若持续增水恰逢天文大潮，则加剧咸潮入侵的影响程度。  相似文献   

2014年秋季渤海网采浮游植物群落结构   总被引：1，自引：0，他引：1  

张雪  王俊  马武  王宏  高燕  刘克奉 《海洋学报》2020,42(8):89-100

基于2014年秋季在渤海进行的水文、化学和生物方面的综合大面调查，研究了渤海网采浮游植物群落的结构特征，并结合文献资料，分析影响浮游植物群落结构形成的原因。结果显示:2014年渤海秋季共鉴定浮游植物3个门42属96种，其中以硅藻为主，为34属79种，占总物种的82%；甲藻门7属16种，占总物种的17%；金藻门1属1种。其中，角毛藻属的种类最多，共17种；其次为圆筛藻属，共13种。浮游植物总细胞丰度介于(0.71～72.15)×104 cells/m3，平均为13.88×104 cells/m3，硅藻与甲藻细胞丰度比值为2∶1，硅藻在莱州湾的细胞丰度极显著高于其他海区，甲藻在渤海中部海区的细胞丰度显著高于其他海区。浮游植物优势种主要为星脐圆筛藻(Coscinodiscus asteromphalus)、威氏圆筛藻(C. wailesii)、具槽帕拉藻(Paralia sulcata)、梭状角藻(Ceratium fusus)和夜光藻(Noctiluca scintillans)。渤海秋季浮游植物群落多样性水平分布不均，局部海域由于单一优势种过量繁殖多样性降低，低值区分布于辽东湾和渤海海峡海域。与历史同期资料对比，渤海海域浮游植物群落出现明显的物种演替现象，甲藻中的角藻逐渐兴起，其在渤海中部及辽东湾的优势地位已经超过角毛藻属和圆筛藻属，渤海秋季局部海区浮游植物群落结构已经由硅藻控制转为硅藻和甲藻共同控制。  相似文献   

南海北部底层沉积物捕获器中海雪和生物粪粒组成及来源探究     

高萌  黄宝琦  刘志飞  赵玉龙  张艳伟 《海洋学报(英文版)》2020,39(3):141-147

Sediment traps are an important tool for studying the source, composition and sedimentation processes of sinking particulate matter in the ocean. An in situ observational mooring(TJ-A-1) is located in the northern South China Sea(20.05°N, 117.42°E) at a water depth of 2 100 m and equipped with two sediment traps deployed at 500 m and 1 950 m. Samples were collected at 18-day intervals, and 20 samples were obtained at both depths from May 2014 to May 2015. Large amounts of fecal matter and marine snow were collected in the lower trap. The fluxes of marine snow and fecal pellets exhibited a fluctuating decrease between May 2014 and early August 2014 and then stabilized at a relatively low level. Scanning electron microscopy observations revealed that the main components of the marine snow and fecal pellets were diatoms, coccolithophores, radiolarians, and other debris, all of which are planktons mostly produced in photic zone. Used in conjunction with the particle collection range estimates from the lower trap and data on ocean surface chlorophyll, these marine snow and fecal pellets were related to the lateral transport of deep water and not vertical migrations from overlying water column. Moreover, the source area might be southwest of Taiwan.  相似文献   

The potential of contribution of mangrove-derived organic matter in intertidal sediments as a proxy of mangrove development in the northern Beibu Gulf     

Jun Zhang  Xianwei Meng  Peng Xia  Xiangqin Wang  Shan Gao 《海洋学报(英文版)》2020,39(12):21-29

Located between terrestrial and marine ecosystems, mangrove forests are sensitive to changes in climate. The responses of mangrove ecosystems to climate change in the future can be understood by reconstructing past mangrove dynamics using proxies preserved in the intertidal sediments. Considering the complexity of the proxies commonly used, it is necessary to develop a relatively simple, inexpensive proxy. In this study, available chemical tracers (δ13C_org and C:N) of the four cores (YLW02, YLW03, O18, and Q37) from the intertidal zone of the northern Beibu Gulf (NBG) and a three-end-member (mangrove, sea grass, and suspended particulate matter) model was utilized to determine the contribution of mangrove-derived organic matter (CMOM) in carbonate-free sediments. Compared with the summed concentration of mangrove pollen (SCMP), a significant positive correlation between CMOM and SCMP is displayed. The calculated CMOM for an additional 210Pb-dated sediment core from the Yingluo Bay, NBG (YLW01) clearly indicates a mangrove development going through degradation, flourishing, relative degradation, and relative flourishing, which are separately in correspondence with the lowest, highest, lower, and higher air temperature and rainfall in the time intervals of 1890–1918 AD, 1919–1956 AD, 1957–1990 AD, and 1991–2010 AD. This suggests that CMOM preserved in intertidal sediments has a potential to reconstruct historical mangrove development in high resolution, at the very least, along the coasts of the NBG.  相似文献   

2012—2016年象山近岸海域水质评价与模拟研究          下载免费PDF全文

叶林安  欧阳萱  陈杲  袁国坚  茆洪卫 《海洋开发与管理》2020,37(3):31-35

为了解象山近岸海域水质污染状况，文章根据2012—2016年象山县近岸海域的水质监测结果，分析象山近岸海域水质现状及年际变化。应用灰色预测的模型来对象山近岸海域水质主要污染物的相关数据进行处理，得出主要污染物的预测结果。分析结果表明：象山近岸海域主要污染物为无机氮。用预测结果和实际数值通过残差验证，最后模拟出今后几年的监测值，为象山县近岸海域生态环境相关管理部门提供数据支撑和决策依据。  相似文献